C2ee03468a 6867..6871

نویسندگان

  • Elizabeth A. Santori
  • James R. Maiolo
  • Matthew J. Bierman
  • Nicholas C. Strandwitz
  • Michael D. Kelzenberg
  • Bruce S. Brunschwig
  • Harry A. Atwater
  • Nathan S. Lewis
چکیده

Arrays of n-Si microwires have to date exhibited low efficiencies when measured as photoanodes in contact with a 1-10-dimethylferrocene (Me2Fc +/0)–CH3OH solution. Using high-purity Au or Cu catalysts, arrays of crystalline Si microwires were grown by a vapor-liquid-solid process without dopants, which produced wires with electronically active dopant concentrations of 1 10 cm . When measured as photoanodes in contact with a Me2Fc – CH3OH solution, the lightly doped Si microwire arrays exhibited greatly increased fill factors and efficiencies as compared to n-Si microwires grown previously with a lower purity Au catalyst. In particular, the Cu-catalyzed Si microwire array photoanodes exhibited open-circuit voltages of 0.44 V, carrier-collection

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تاریخ انتشار 2012